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This potential difference vanishes at higher potentials.
Oxidation of (A) at higher potentials follows two possible routes.
At higher potentials, macrostructures consisting of micron-size depressions appear.
Higher potentials values are required at lower electrolyte concentrations.
These changes take place at higher potentials of degradation.
Generally, most coupons presented higher potentials after 12 weeks exposure which indicated a more stabilized state, knowing that lower E corr values suggest a higher corrosion risk46, 47.
At higher potentials less current was generated, although more biomass was formed on the electrode.
Jarosite precipitation on the electrode surface hindered the dissolution of chalcopyrite at higher potentials.
However, at higher potentials, the oxidation reaction of adsorbed intermediate COads becomes rate-determining step.
CO oxidation takes place only at higher potentials shifting negatively with increasing coverage.
In comparison, the Tafel slope increased gradually to 250 mV dec−1 at higher potentials.
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