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Ca2+ and Sr2+ ions are much bigger, have higher coordination numbers (seven-coordinated Ca2+ 2.00 Å, eight-coordinate Ca2+ 2.17 Å, ten-coordinated Sr2+ 2.33 Å), and the bonds are less directed.
Structurally, Au(I) predominantly forms linear two-coordinate complexes, although higher coordination numbers are also possible.
When metal ions with higher coordination possibilities are applied instead, 2D and 3D networks are generated.
Coordination numbers from 2 to 9 have been observed in complexes; higher coordination numbers occur, although rarely.
Unlike TS-1 cathatsts that mainly contain isolated Ti4+ ions in tetrahedral lattice positions, TS-PQ™ silicate contains tetrahedral and higher coordination Ti4+ ions.
We also noted that lower coordination clusters prefer Cu as the central atom whereas higher coordination clusters prefer Zr as central atom to minimize the bond energy.
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In this case, the change in shape of the B K-ELNES indicates that B K-ELNES hindicatesrdinathats than planar trigonal together with possiboronome residual sp2 sites.
Lanthanide(III) ions are known to take high coordination numbers such as 7 10 with the most popular coordination geometries being octa-coordinate square antiprism and the ennea-coordinate tricapped trigonal prism geometries [67].
Monte Carlo simulations of linear and cyclic alkanes were performed on a coarse-grained high coordination lattice.
The simulation employs coarse-grained chains, with one bead for each repeating unit, on a high coordination lattice.
In compound 1, twelve surface oxygen atoms of [VMo7O26]5− cluster are utilized to make coordination linkage with other components; creating the highest coordination connection in molybdovanadates subfamily.
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