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Thermal energy required to break up the hydrogen bonds and to permit vaporization is available only at the higher boiling temperatures.
An interesting application, though not of great commercial significance, is the use of mercury vapour instead of steam in some electrical generating plants, the higher boiling point of mercury providing greater efficiency in the heat cycle.
Alkynes have higher boiling points than alkanes or alkenes, because the electric field of an alkyne, with its increased number of weakly held π electrons, is more easily distorted, producing stronger attractive forces between molecules.
Thus, a hydrophobic surface has a higher boiling heat transfer coefficient (BHTC) than a hydrophilic surface.
Resids have increased molecular weight (MW) and higher boiling point fractions and need more energy to vaporize them to enter the catalyst riser.
As to the glycol dispersions, considering the higher boiling point of the base fluid, a higher stability was observed up to 150°C, where only a weak aggregation started.
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This series is an important part of all liquid refinery products, but it also forms most of the complex residues from the higher boiling-point ranges.
Thus, volatile components such as methane, water, and N2 coalesced into outer solar system bodies such as the gas and ice giant planets (Saturn, Jupiter, Neptune, and Uranus) and the Oort cloud and Kuiper belt comets, while higher boiling-point compounds such as metal oxides and silicates, which make up the bulk of the inner rocky planets, condensed nearer in.
A generally good correlation with the boiling point of the higher-boiling component is clear with an exception of water, which is apparently less effective in the cation removal.> -wrap-foot> Boiling points: DCM (dichloromethane), 40 °C; MeOH, 65 °C; DCE (1,2-dichloroethane), 84 °C; PrOH, 97 °C; water, 100 °C; 1,4-dioxane, 101 °C; toluene, 111 °C; DMF, 153 °C.
Another requirement, that a quality gasoline have a high energy content, has traditionally been satisfied by including higher-boiling components in the blend.
Higher-boiling materials were found to be effective as lubricants and fuel oils, but they were largely novelties at first.
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