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High resolution electrospray ionization mass spectrometry.
The reaction has been studied and intermediates characterized using; 13C, 1H, and 17O NMR, and high resolution electrospray ionization mass spectrometry (HR ESI MS).
Compound 1 was obtained as yellow crystal (CH3OH), with the molecular formula C13H14O6 as determined by high resolution electrospray ionization mass spectra (HR ESI MS) at m/z 289.0681 [M + Na]+, indicating the presence of seven degrees of unsaturation.
An improved design for high resolution electrospray ionization ion mobility spectrometry (ESI-IMS) was developed by making some salient modifications to the IMS cell and its performance was investigated.
The experimentally observed changes in the spectral properties of the probe upon addition of CN− were systematically studied using high resolution electrospray ionization mass spectrometry (HR-ESI-MS), proton nuclear magnetic resonance (1H-NMR), and time-dependent density functional theory (TDDFT) calculations.
The experimentally observed changes in the spectral features of the probe upon addition of SO32− were systematically studied using high resolution electrospray ionization mass spectrometry (HR-ESI MS), proton nuclear magnetic resonance (1HR-ESI MSnd time-deprotont denuclearunctional theory (TDDFT) calculations.
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The high-resolution electrospray ionization (ESI) mass spectrum of dendron 18 showed the anticipated protonated molecular ion peak at m/z 3254.466 as [M+H+].
High-resolution electrospray ionization mass spectrometry was performed using a Agilent G6550 QTOF AgilenttechnologieseSanta Clara, CACA, USA) equipped with an ESI inter-face.
A high-resolution electrospray mass spectrometer (MicrOTOF-Q II, Bruker Daltonics Corporation, USA) was operated in negative ion mode for mass spectrometer analysis.
Its molecular formula was determined to be C18H20O3 from high-resolution electrospray ionisation mass spectrometry (HRESIMS) (m/z 283.1365 [M − H]−).
The identities of peptides were confirmed with high-resolution electrospray ionization mass spectrometry (HR ESI-MS), and the data are shown in Additional file 1: Table S1.
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