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The resulting membranes displayed high hydroxide conductivity, while other fuel cell related properties are not so excellent.
A high hydroxide conductivity of 47 mS/cm at 25 °C and 85 mS/cm at 80 °C was achieved.
Their high hydroxide conductivity is attributed to the greater length and dense distribution of the pendant benzyl-quaternary ammonium groups.
The crosslinked membranes maintained high hydroxide conductivities despite their extremely low water uptake (up to 57.5 mS cm 1 at room temperature, water uptake of 34.5 wt%).
The membranes showed high hydroxide conductivity (10.4 mS cm−1) despite their low ion exchange capacity (IEC, 0.98 meq g−1).
Especially, the PBI/DAIm TIPN-65/0.5 TIPN-65/0.5hibits high hydroxide conductivity (96.7 membrane and low swexhibitsatio (4.4%) at 80 °C.
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Compared with TA-PPO membrane, the Im-SiO2/TA-PPO composite membrane exhibits the higher hydroxide conductivity and dimensional stability, and even higher alkaline stability and oxidation resistance.
Moreover, the QQBPES-2.4OH membrane exhibited considerably higher hydroxide conductivity, up to 68.0 mS cm−1 at 80 °C, better flexibility and lower water swelling.
The QAPPO/8% IL-SiO2 composite membrane exhibits the highest hydroxide conductivity of 70.2 mS cm−1 at 80 °C and the lowest activation energy of 12.1 kJ mol−1.
A higher hydroxide ion concentration results in a lower bond strength between the surface and the adsorbed thiocyanate ion.
The TQAPEK-0.5 membrane with ionic exchange capacity (IEC) of 1.94 meq g−1 shows the highest hydroxide conductivity of 132.8 mS cm−1 at 80 °C.
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