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Fitting the results with Freundlich model reflected heterogeneous surface and adsorption into a porous material.
The Freundlich adsorption isotherm is a special case for heterogeneous surface and is usually used to model adsorption from solution.
In the Freundlich isotherm, a heterogeneous surface and a multilayer adsorption on the adsorbent surface are assumed.
BMO thin films produced by an electrochemical method showed a heterogeneous surface and grain sizes varying from 2 to 10 μm [12].
Freundlich model is based on the sorption of solute on a heterogeneous surface and involves the interaction between the molecules of the adsorbate.
The Freundlich isotherm is a result of the assumption that the adsorption occurs on a heterogeneous surface and non-uniform distribution of the heat of adsorption over the adsorbent surface takes place (Mittal et al. 2010).The Freundlich isotherm is expressed as (Freundlich 1906) log q_{e} = log k + frac{1}{n}log C_{e}.
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The Freundlich isotherm describes equilibrium on heterogeneous surfaces and assumes a monolayer adsorption capacity [40].
The Freundlich model relates the sorption of an adsorbate to heterogeneous surfaces, and it assumes a multilayer adsorption (Freundlich and Helle 1939).
The Freundlich isotherm is often used for modeling the multilayer adsorption on heterogeneous surfaces and also applied for the very low concentration.
Freundlich isotherm depict non-ideal sorption on heterogeneous surfaces and is stated by the following equation: q_{text{e}} = K_{text{F}} C_{text{e}}^{{frac{1}{n}}}.
According to adsorption isotherms, the equilibrium adsorption data correlates well with Freundlich isotherm model, which describes multilayer adsorption on heterogeneous surfaces, and Langmuir isotherm model that illustrates monolayer adsorption in the given Pb2+ ion concentration range.
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