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For the sake of comparison, an alkanethiol (H18SH) was also examined, and F10H10COOH and F10H10OH molecules were used for helping the assignment of SFG spectra of CH stretches.
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Vibrational analyses reveal strong features that are characteristic of each site, which may help in the assignment of experimental spectra.
An optimal local alignment would help in the assignment of residue-residue equivalences more precisely.
The figure which occludes parts of the background leads to specific boundary configurations, in particular T-junction configurations which can help in the assignment of figure and background.
The concurrent formation of the reduced peptides helps confirm the assignment of the precursor cross-links.
The presence of ions of the next or preceding oligomer can also help confirm the assignment of the charge state.
The inclusion of methyl-methyl NOEs can help for the assignment of large perdeuterated, methyl protonated proteins.
Next to their pronounced effect on ionization, labels influence the fragmentation behavior of glycans and may help with the assignment of fragmentation spectra by tagging the reducing end.
Overall, genes without significant annotation were specifically attributed to a tissue based on their expression pattern, which can provide valuable help towards the assignment of gene function.
The availability of the tridimensional structures of a large number of proteins, obtained mainly by X-ray crystallography, can be of help for the assignment of the N- H NMR spectra.
For these reasons, in this work, we asked the help of a professionally trained Brazilian Musician to help us with the assignment of mood labels to each song in the LMD, creating the Latin Music Mood Database.
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