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Thermodynamic comparison of the selected adsorbents was carried out on the basis of the experimental measurement of the main thermo-physical parameters, such as specific heat, adsorption equilibrium curves and sorption enthalpy.
The results show that the heat adsorption and heat emission of an underground hydroelectric station's building enclosure must be considered when determining the design heat load of the generator hall and water turbine room; the contrary is true for the busbar chamber and transformer pit.
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The design of adsorptive heat transformers (adsorption heat pumps and chillers and adsorption thermal energy storage) requires knowledge on the heat and mass transfer resistances in adsorbents.
The heat of adsorption and entropy of adsorption are important parameters for understanding adsorption of organic inhibitors at metal/solution interface.
The CO2 heat of adsorption was evaluated using the adsorption isotherms measured at 273 and 313 K in accordance with the Clausius Clapeyron equation.
The activation energies, heat of adsorption and the entropy of adsorption of hydrogen and various liquid phase components were evaluated.
The equilibrium sorption data can fit well with the Langmuir model based on the value of correlation coefficient R. The Freundlich model assumes a heterogeneous surface with a nonuniform distribution of heat of adsorption over the surface, and the adsorption sites are distributed exponentially with respect to the heat of adsorption [ 36].
Heat of adsorption is a characteristic property of the adsorption process and more specifically to type of adsorption and the extent of adsorption.
The Temkin isotherm shows that the heat of adsorption is low (9.72 J mol−1) indicating physical adsorption.
The Temkin isotherm, B, of both derived and thiol-functionalized silica (Table 2) shows that the heat of adsorption increases with increase in temperature, indicating endothermic adsorption.
The calculated isosteric heat of adsorption of 191.9 meV on graphite [73] and adsorption energies of 209.9 or 181.7 meV calculated with two different potentials [74] agree well with the experimentally determined isosteric heat of adsorption of 211 ± 2 meV extrapolated to zero coverage [6].
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