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Discover Ludwig'had proven' is correct and usable in written English.
It is typically used as part of the past perfect tense to describe an action that happened before something else in the past. For example: "The detective had proven that the suspect was guilty before the jury reached their verdict."
Exact(60)
No other drug had proven as effective.
In that, at least, it had proven effective.
He, of course, had proven that months ago.
The recruits, many of them teenagers, had proven disastrously undisciplined.
Other communist-era relics had proven less robust.
He clearly thought that the P.K.K. had proven itself.
Anyway, he had proven a much more suitable Captain Clean.
Athens was a walled city which had proven itself capable of defending those walls.
And they had to change bureaucratic procedures that had proven ineffective.
But at the end of 2014, the US had proven reserves of just under 40bn barrels, while Saudi Arabia alone had proven reserves of 268bn barrels.
Last fall, she had proven herself capable of beating Kwan when she won Skate Canada.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com