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Therefore, when an OH group transfers, it must leave an electron behind, reducing the iron, and then reaccept an electron from chromium, oxidizing it.
In addition to the aromatic and aliphatic hydroxylations, N- and O-dealkylations, and heteroatom oxidations that are common in drug metabolism, many more unusual reactions catalyzed by P450s have been discovered, including reductions, group transfers and other biotransformations not typically associated with monooxygenases.
MeB12 promotes methyl (-CH3) group transfers.
Wali gestures to a folder in his cabinet labeled "Seychelles," detailing two group transfers from that nation to Somaliland over the past couple of years.
Cluster #7 is related to acyl group transfers and CoA ligation.
Importantly, thioesters, often used in nature for acyl group transfers (including in nonribosomal peptide synthesis), are soft electrophiles.
Similar(50)
CommComm's been offered a group transfer to naivac Omaha.
Fernández, I., Sierra, M. A. & Cossío, F. P. In-plane aromaticity in double group transfer reactions.
Board a private motor coach for a group transfer to Avignon.
OBERHAUSER: I was there until the command of the army group transferred its headquarters farther west.
The Abrons group transferred the midblock parcel to Rheinstein, who had built commercial buildings, among them 21 West Street.
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