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Antibody binding to a high-entropy molecule would require a greater activation energy than binding to a lower-entropy molecule and may thereby introduce structural or functional constraints in either the FWR or CDRs.
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Linear kinetics with activation energies of 90.4 and 78.9 kJ/mol were obtained for mc-WC and nc-WC, respectively, while oxidation kinetics of Ni/mc-WC and Ni/nc-WC coatings obeyed the parabolic law with greater activation energies of 212 and 197.5 kJ/mol.
The different photocatalysts exhibited different temperature sensitivities with the Hombikat supported Au showing the greatest apparent activation energy.
The generation 2 and 3 polymers exhibit greater flow activation energies than the generation 4 and 5 materials due to stronger polar interactions.
From real time analysis, it was found that effects of electron energy and ion energy on methane conversion were minimal when the electron energy of plasma is greater than methane activation energy.
It is demonstrated that all the alloying elements influence, to a greater or lesser extent, the activation energy (Q).
Aliphatic hydrocarbons appear to contribute more to heat release during coal oxidation due to greater heat release and lower activation energy of their reactions.
These studies show that temperature and activation energy have a greater impact on optimal geometry than parameters like pressure or feed fuel fraction for the selected oxygen carrier materials.
The results can be explained if the mechanisms of toxicity involves a redox reaction, since it would be expected that the least toxic compound (lowest electron affinity) would have the largest activation energy and hence the greatest temperature effect.
It can be seen that a lower activation energy (Ea) leads to a greater probability of a nonradiative transition.
In both cases, the activation energy for the nanocomposite sample is greater than that for the neat nylon 6.
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