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The surface grafting processes were all performed in water (i.e. without organic solvent).
Recent achievements in using nitroxyl derivatives in degradation, polymerization and grafting processes are discussed together with the involved chemical reactions and the resulting material properties.
Nevertheless, there is a lack of knowledge concerning the efficiency of the grafting processes, and more specifically concerning the question of the competition between covalent and non-covalent grafting.
Meanwhile, single filament tensile strength (TS) had no obvious decrease after the grafting processes.
The hyperbranched polyester was grafted to the surface of indium tin oxides glass (ITO) electrode, and the grafting processes were characterized by attentuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM).
Grafting through or surface grafting processes were achieved by varying the water fraction in the initial monomer solution.
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Fig. 3 Example of current density vs time for potentiostatic method used for grafting process.
Fig. 2 Example of current density vs. potential for five cyclic voltammograms used for grafting process.
The electrochemically assisted grafting process of glassy carbon (GC) surfaces is pursued by using the 7-[ 5,5′-diiodo-2,2′-bithiophen-4-yl)sulfanyl]heptanenitrile (DIBHN).
On the other hand, partial neutralization of hydroxyl groups occurred on the support surface by grafting process, and the neutralization reaction is practically complete at 25 wt.% of Nb2O5 by impregnation.
Kinetic studies of homogeneous (in toluene solution) system revealed a linear increase in molecular weight with the reaction time and narrow molecular weight distribution, indicating that the chain growth from the membrane surface was a "controlled" or "living" grafting process.
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