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Fig. 3 Example of current density vs time for potentiostatic method used for grafting process.
Fig. 2 Example of current density vs. potential for five cyclic voltammograms used for grafting process.
The electrochemically assisted grafting process of glassy carbon (GC) surfaces is pursued by using the 7-[ 5,5′-diiodo-2,2′-bithiophen-4-yl)sulfanyl]heptanenitrile (DIBHN).
Kinetic studies of homogeneous (in toluene solution) system revealed a linear increase in molecular weight with the reaction time and narrow molecular weight distribution, indicating that the chain growth from the membrane surface was a "controlled" or "living" grafting process.
It was revealed that there is equilibrium of grafting of GMA and depolymerization of grafted PGMA chains in the GMA/polyolefin grafting process, which was affected by both of the temperature and GMA concentration.
In comparison with traditional molten grafting process, the work presents a novel approach to increase the grafting efficiency of MAH and control the molecular weight of resultant PP-g-MAH simultaneously.
-1 for every guide atom involved in the grafting process.
The changes in chemical composition and morphology of the membranes' surface indicated the successful grafting process.
A systematic study of the reaction variables allowed the optimization of the grafting process.
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Poly d,l-lactide-co-glycolide -b-poly l-histidine -b-poly ethylene glycol) (PLGA-PLH-PEG) was synthesized by a sequential end-grafting process.
The above steps compose one cycle of Al2O3 grafting, and the Al2O3-grafting process can be repeated several times.
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