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Based on the bond dissociation energy calculation, these compounds exhibit good detonation performance.
DNAN is less sensitive to shock, high temperatures, and has good detonation characteristics.
The detonation properties of the PBX decreased with the increasing W%, and the PBX with 4.69% F2314 was regarded with good detonation properties.
These compounds exhibit large solid-phase heats of formation (656.27 854.12 kJ/mol), high crystal densities (1.80 2.00 g/cm3) and good detonation performance (detonation velocities over 8.84 km/s, detonation pressures over 34.65 GPa).
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Still, in these very contradictions there is no mistaking an Irving novel, though it's hard to say what such a thing might be other than a good-sized detonation that leaves a relatively shallow crater.
Measured phase velocities are in good agreement with Detonation Shock Dynamics (DSD) predictions for PBX 9501.
Furthermore, the model offers a good prediction for detonation initiation in the presence of shock waves when compared to high and low-resolution 1D-NS simulations.
It is found that there are good linear relationships between detonation velocity, detonation pressure and the number of nitro group.
1,1′-diamino-2,2,2′,2′-tetranitro-1,1′-azoethylene (M1) was recommended to be very promising energetic materials for its good stability and excellent detonation properties: the HOF is 648.6 kJ/mol, the crystal density is 1.95 g/cm3, the HOD is 5.66 kJ/g, the VD is 9.68 km/s, the PD is 43.42 GPa and the RIs is 1.077.
It is found that there are good linear relationships between volume, density, detonation velocity, detonation pressure and the number of nitro group.
For hydrogen-oxygen spherical detonations, this critical radius is about 500 times larger than the thickness of the planar CJ detonation front, in good agreement with our theoretical results based on a one-step reaction model.
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