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Thus, both DMSO and dimethyl sulfone (and related alkyl sulfoxides and sulfones) undergo loss of a proton to bases such as sodium hydride (NaH2), giving the corresponding salts e.g., CH3S(O)CH2Nandnd CH3SO2CH2Na.
The catalyst 1 promotes the copolymerization of β-myrcene with styrene giving the corresponding copolymers in a wide range of composition (χs = 0.14 0.90).
Its cationic iridium complex has been characterized by X-ray diffraction analysis and evaluated in the catalytic asymmetric hydrogenation of alkene and imine derivatives, giving the corresponding hydrogenation products with high activity albeit moderate enantioselecitivity.
For instance, the use of only 0.1 mol % of (S -2 waS -2fficient to complete the reaction betwasn acetone and 4-nitrobenzaldehyde, giving the corresufficientldol adductoin good yield with an excompleteenantheselectivity.
Schiff base L3 showed high efficiency in Fe(III -catalyzed asymmetrIII -catalyzedonylasymmetricaldehydrophosphonylationsrespofding products in high yields (up to 91%) aldehydesh moderate to givingnantheselecorresponding to 82%).
Under optimized conditions, these chiral ruthenium complexes serve as catalyst precursors for the asymmetric transfer hydrogenation of acetophenone derivatives in iso-PrOH and act as excellent catalysts, giving the corresponding chiral alcohols in 99% yield and up to 75% ee.
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Figure 5 gives the corresponding numerical simulation.
Let us give the corresponding example.
Figure 4a gives the corresponding Nyquist plots.
Subsequent hydrogenation gave the corresponding ethylene-co-aryl ether polymers.
Further oxidation of studied compounds gave the corresponding sulfoxide.
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