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The current in-situ generated catalyst systems feature high productivity, selectivity, robustness (e.g. high thermal stability, good tolerance to poisons and environmentally friendly hexane as solution polymerization medium) and single-site behaviour.
Catalyst 4 or in situ generated catalyst give comparable results for conventional heating at 65 °C (Entries 9, 10).
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Prior studies have shown an effective way to produce diverse ligand sets for catalyst discovery is by using mixtures of monodentate forms to generate catalysts in situ.
In the sol gel catalysts the main effect produced by the presence of copper is to modify the porosity of the solid, generating catalysts with high microporosity.
By comparison, Catalyst II had a far larger hysteresis loop than that of Catalyst I, which indicated that more mesopores were generated in Catalyst II.
Docking and scoring: low energy conformations of the chemical compounds were generated using Catalyst (Accelrys, Inc).
In this work we demonstrate an in situ generated growth catalyst that produces highly oriented graphitic nanowiggles (GNWs).
The rehydration of the Mg,Al-mixed oxide generated a catalyst that was selective to the condensation product of glyceraldehyde acetonide and acetone.
The conformational models for this validation dataset were generated within Catalyst 4.11 with a maximum number of 100 conformations per molecule and 'FAST' quality.
Hypogen PXR pharmacophores for each species were generated with Catalyst™ using the 16 molecules in Table 4. Molecules highlighted in bold type were used for training as they are common to all species – molecules with no effect were given the arbitrary EC50 value of 10,000 μM (10 mM).
They started by mixing a plastic-generating catalyst along with reinforcing fibers into a soft epoxy resin.
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