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Luminescence studies reveal absolute quenching of the excited state upon deprotonation in accordance with the energy gap law.
We propose three reasons for the simplicity of vibrationally resolved electronic spectra of complex chain molecules: vibr onic) state localization, insensitivity of chromophores to conformational changes outside the chromophore, and an 'energy gap law' for low-lying conformers.
In addition, according to the energy gap law, the absorption-emission Stokes shifts as well as energy gaps between T1 and S0 states were also computed to describe the nonradiative decay processes qualitatively.
We have investigated photoinduced electron transfer and related processes from the higher excited electronic state (S2) of Zn-porphyrin-imide acceptor directly linked supramolecular systems (ZP-I) designed especially for the critical studies of the energy gap law (EGL) of the charge separation (CS) from the S2 state and solvent effects upon EGL.
However, the luminescent quantum yields of red-emitting iridium III) phosphors tend to be intrinsically low which are governed by the energy gap law for triplet states in which the luminescence quantum yields tend to decrease with an increase in the emission wavelength.
The increase in quantum yield and blue-shifted emission demonstrated by 2 are consistent with the energy gap law and suggest the ancillary ligands have a considerable effect on the MLCT excited state, consistent with our previous studies on Ru dppz -based systems incoRu dppz -basednded polypyridyl ligandsystems
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