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Complexes 1 4 show similar 2D, non-interpenetrated, uninodal 4-connected layers that are further connected by H-bonding interactions to 3D supramolecular structures.
The single-crystal structure analysis reveals that this framework features novel Ln8Na and Cu8I clusters as nodes, these nodes are further connected by the CPT ligands to give rise to a (6,14 -connected network.
The layers are further connected by C H···π interactions into three dimensional supramolecular architectures, respectively.
The 2D layers are further connected by μ2-TTA2− ligands to give a 3D (42.64)(42.67.8) topological structure.
Complex 2 shows 1D zigzag chain, which is further connected by hydrogen bonds to form a 3D supramolecular net.
The neighboring Cu Gd Cu chains are further connected by hydrogen bonds to form a two-dimensional structure.
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After that, the complete set of 43,845 'decontaminated and rescued' sequences, which had a total length of 829.0 Mb (Supplementary Table S2), were further connected as super-scaffolds by using the Illumina MP reads and SSPACE 2.0.
The 2-D sheets are further connected into 3-D architecture by noncovalent interactions.
Compounds 3 and 4 are further connected into 3D supramolecular network by hydrogen bond interactions.
For compound 2, every nbta3- anion connects three ZnII ions to give a 2D layer structure, the 2D layers are further connected into a facinating 3D framework by biim ligands with (3,4 -connected (3,4 -connected7·8)(3·6·76·8·9)(5·6·8·10·112) topology.
Compound 1 possesses two diverse 1D chains constructed by different bipy coligands, which were further connected to form a 3D supramolecular architecture by hydrogen bonding interactions.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com