With a chosen trial wave function, an explicit expression can be worked out for the local energy E L (R) E in terms of the values and derivatives of Ψ.
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Its asymptotic behavior and other properties of this function can be seen from the works of [23, 24] and [25].
The memory effects have strong relationship with the work function, and the work function can be modulated by changing the metal species.
From the work of Novikov [16], the value of the intrinsic work function can be obtained, E i = 4.78 ± 0.08 eV.
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The variation of the work function can be understood from the change of the Fermi level.
Evac is determined as the asymptotic value of this average electrostatic potential energy, and then the work function can be obtained by using its definition.
If the tip surface potential is calibrated, then the absolute values of the surface potential (and then the work function) can be obtained.
Ultraviolet photoelectron spectroscopy measurements also show that the LSMO work function can be modified by surface dipoles opening the door to both tune the charge and spin injection efficiencies in organic devices such as organic light-emitting diodes.
