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The fragments originate from the fragmentation channel (Scheme 7) of ions at m/z 191, m/z 174, m/z 118, and m/z 106 may be used to determine the structure of the side chain, while those produced from the fragmentation channel of ion m/z 178 may be used to determine the substituent groups localized on thiazine ring.
If an MS/MS experiment without ion mobility separation is performed, the resulting spectrum will contain a mixture of fragment peaks from the fragmentation of both species.
The efficiency of the loading machines was also correlated with the mean fragment size obtained from the fragmentation analyses.
The number of sequences resulting from the fragmentation, and the N50 size of the fragments were calculated (Additional file 5: Table S2).
As a comment to Fig. 1, it is important to mention that no specific fragment ion could be identified to differentiate the two isomers of diosmetin glucuronides, both in positive and negative ionizations; the fragments coming from the loss of glucuronide and then from the fragmentation of diosmetin (in particular by elimination of the methyl group, methanol, or dioxole) being the most relevant.
The validity of the Kelly and Tyson model for the calculation of IFSS from the fragmentation (SFFT) test requires that the samples are fully saturated with fragments [ 28].
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While different than those from CID, the fragmentation patterns from ETD also support our proposed cross-linking site and chemistry.
It and they are fragmented, though the fragmentation varies from book to book.
It is space to heal the fragmentation from the sensory and social battering that being in the world causes me.
Their photographs show pockmarks consistent with the fragmentation from barrel bombs, and what appears to be the tail fin of a Russian-made OFAB-250-270 airdropped bomb, a type that Russian planes in Syria have been filmed carrying.
Clayton, a survivor of the first blast, had wandered out of the school building debris and was killed by the fragmentation from the exploding vehicle.
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