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The crystal structure of the synthesized LSMO nanoparticles was characterized by X-ray diffraction (XRD) (Philips PW3040, The Netherlands) with the crystallite size calculated from the broadening of the XRD peaks using Debye Scherrer method.
The crystallite size was estimated from the broadening of XRD peaks, using Scherrer's formula (2) [7].
The crystallite size, d (hkl), was calculated from the broadening (FWHM) of the (311) reflection following the Debye-Scherrer equation, resulting to be d (311) ≈ 12 nm.
The crystallite sizes of the Au-sputtered ZnO-NRs, estimated from the broadening of XRD peaks, are about 57.14 nm, whereas AuNP has 7.6 nm.
The mean crystallite size is determined from the broadening of the diffraction peaks (311) and (400) plane using Debye Scherer's formula [16].
From the broadening peak at 2θ = 51.8°, the particle metallic size are lower for Ni(n w), Ni(a w) and Ni(n e) samples.
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The linewidth is also distorted by the high-energy tail, indicating that the spectral broadening results mostly from the thermal broadening.
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