Sentence examples for free coordination from inspiring English sources

A polar, coordinating solvent such as acetonitrile (entry 6) competitively coordinates to the dicationic platinum catalyst and hinders access to the free coordination site on platinum.

When they have a ligand group adjacent to a carboxylic acid group, two different metal complexes can be introduced into a monolayer: a complex with a free coordination site can be bound via the ligand group, and a cationic complex as counter-ion.

However, as iron still had a free coordination site for oxygen, a mechanism wherein catechol dissociates was not considered.

In most cases, the chelated GdIII ion presents a free coordination site that can be occupied by water (Table 1).

The [(L Ru2III,IV pic)4(OH)]+ species thus contains a free coordination site, which should enable the coordination of a second aqua ligand.

POM-complexes consisting of more than one metal exhibiting Lewis acidity or more than one POM (e.g. Zr(IV 2 POM2) are prone to dissociate in solution, especially under acidic conditions, into monomeric complexes (Zr(IV 1 POM1) leading to a structure with an accessible hydrolytic metal containing free coordination sites (Fig. 6A) [56 58].

Thus, our results show that P-free coordination compounds and commercial organic precursors can act as efficient carbon source for the growth of NCFs.

One singularity-free coordination is the unit quaternion; (q=left[ q_0,,, e^Tright] ^Tin mathbb {R}^4) where (q_0in mathbb {R}) is the scalar part and (e=left[ q_1,,, q_2,,, q_3right] ^Tin mathbb {R}^3) is the vector part with (Vert qVert _2 =1).

Although one end of the glycine molecule is free from coordination, the structure is highly stable up to 350 °C.

In this paper we develop a broad framework for NIS analysis, involving free market, coordination and complex-evolutionary system approaches.

Ramachandran maps are constructed for the sampled Pt-Aβ conformations and secondary structural analysis of the obtained complex structures is performed and contrasted with the free peptide; coordination of these platinum complexes disrupts existing secondary structure in the Aβ peptide and promotes formation of ligand-specific turn-type secondary structure.