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The δ34S fractionation follows a Rayleigh fractionation model with an enrichment factor of 21.6‰.
These results suggest that the carbon isotope fractionations of these compounds during vaporization from a multi-component system (the artificial oil) followed the Rayleigh fractionation model.
Isotope fractionations ranged from 9‰ to 34‰ and correlated inversely with SRR, as predicted by the standard fractionation model for enzymatic sulfate reduction of Rees (1973).
Vaporization significantly enriched the 13C present in the remaining components of the C6 C9 fraction, indicating that the vaporization is mainly kinetically controlled; the observed variations could be described with a Rayleigh fractionation model.
In order to validate our fractionation model empirically, we will have to expand it to incorporate the rearrangement events that are pervasive in genome evolution.
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In the case of dispersed metal droplets that continuously re-equilibrated as they sink in a magma ocean, more realistic fractionation models have been proposed according to which the effective equilibration pressure differs significantly from the pressure at the base of a magma ocean (Rubie et al. 2003).
The successful application and interpretation of carbon isotopes rely on the coherence of isotopic fractionation modeling.
Carbon isotopic signatures highly depend on cell metabolism, and their interpretations rely on the rationale of the correct isotopic fractionation modeling.
The isotopic fractionation was modelled by formulating separate reaction networks for lighter (12C) and heavier (13C) isotopes.
The incorporation of isotope fractionation in the model better enables to account for other natural attenuation processes, such as dilution and dispersion, in EIB applications at field scale.
The demonstrated synthesis of compulsive checking by the combined treatment of low-dose DPAT and NAc lesion strengthened the previous fractionation of the model obsessive-compulsive disorder phenotype into three constitutive components, and suggested a role for serotonin-1A receptors outside the NAc in enhanced focus on the task of checking.
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