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A paradigmatic example is that hexa-alkyl substituted triphenylenes present mesogenic behavior [1, 3, 4], while the corresponding azatriphenylenes, notwithstanding the apparent similarity in shape and chemical structure with the former compounds (see Figure 1), do not form any liquid crystalline mesophase [5] if not enforced by adding hydrogen bonding side groups [6, 7].
UV excitation of the two former compounds leads to polymerization at the triple bond as a major process to yield, respectively, saturated poly trimethylsilyloxyhydrocarbon) and poly trimethylsilylhydrocarbon), whereas that of the latter compound is controlled by cleavage reactions to afford poly methylsiloxane).
However, the increase of the cage strain energies of polynitroadamantanes is less drastic than that of polynitrocubanes; on the contrary, the decrease of the bond dissociation energies of C NO2 bonds in the former compounds is more rapidly than the latter.
The fungal cell wall is composed of glucans and chitin; while the former compounds are also found in plants and the latter in the exoskeleton of arthropods, fungi are the only organisms that combine these two structural molecules in their cell wall.
The similarity of 11 to the former compounds is 0.7 at maximum.
These new drugs are active against HIV variants resistant to former compounds and generally exhibit better safety profiles.
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And later, as a very rich man, he bought classy real estate, including Andy Warhol's former compound at Montauk.
Hayden Lake, a community of about 400 people that is 10 miles south of the former compound, has probably borne the biggest brunt of the image problem.
Its confident, with-it moniker became the driving force behind the recent popularization of the phrase with the former compound adjective, now an attributive noun: Boldface Names.
The former compound of a single clan might become home to two dozen families, and the city's population swelled with new arrivals.
Borrowing his brother's motorcycle, Hikmat drove out to the former compound of the Taliban leader Mullah Omar, in the hills north of the city.
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