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Hydroacylation, the formal addition of an aldehyde CH bond across an unsaturated functional group, is an ideal approach to carbonyl functionalities commonly found in bioactive molecules.
Structural analysis shows that these complexes are reduced by the formal addition of one hydride ion to each imino group, resulting in a deprotonated bis amido)pyridyl-thiolate ligand.
This indicated formal addition of a CH2O unit to 4 epi.
This reaction can be interpreted as the formal addition of a phosphide and a carbonyl across the Si=Si double bond.
This was consistent with a molecular formula of C35H40N4O9, as found in the HO-NCC 6 epi, suggesting the formal addition of an oxygen atom to 4 epi.
Analyses by positive ion ESI mass spectrometry showed a pseudo-molecular ion [ M+Na]+ at m/ z 697.4, consistent with its molecular formula as C36H42N4O9 (and indicating the formal addition of a CH2O unit to 4 epi ).
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An upper-case letter indicates formal addition or substitution of a structural part.
In 2005, MacMillan and co-workers reported a combination of transfer hydrogenation using Hantzsch ester and electrophilic fluorination using NFSI on enal substrates, which would allow the formal asymmetric addition of HF across trisubstituted olefin systems using a cascade-catalysis approach (Scheme 40).
The addition of formal charges signals that authorities plan to bring him to trial — a demonstration of how acutely uncomfortable the Party is with the idea of plutocrats with opinions.
After the formal union and the addition of deputies from the Grand Duchy, and Royal Prussia, also more fully integrated with the Crown in 1569, there were about 170 regional deputies in the lower chamber (referred to as the Sejm) and 140 senators.
Further development, including the addition of formal evaluation of patient and carer outcomes is underway and will be reported at a later stage.
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