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The GC-content differed between the two species, with G. aculeatus at 55% while Z. viviparus had 48% for the contigs but only 43% for the singlets.
In total 2116 particles were collected of representative doublet particles and these were aligned and classified in the same manner as for the singlets.
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Bimolecular rate constants for the singlet and triplet quenching of thioxanthone by the amine were determined using fluorescence and laser flash photolysis techniques.
An analysis of decay data from fs pump-probe experiment yields a value of 164 ps for the singlet excited state lifetime of the Pdots.
UV Vis absorption spectra for the singlet-singlet transition computed for fully optimized ground state geometry using Time-Dependent-Density Functional Theory (TD-DFT) with CAM-B3LYP functional was found to be in consistent with that of experimental findings.
The results for the singlet distribution and the mean orientation functions of charged dimers at the negative electrode show that the large diameter of neutral spheres stabilizes the perpendicular orientation of dimers with charged spheres closer to the electrode.
The individual rate constants for the reactions involved in the photoinitiation process have been determined by static fluorescence for the singlet state and flash photolysis for the triplet states.
For clusters with an even number of hydrogen or fluorine atoms (even number of electrons), the computations were performed for the singlet multiplicity only, whereas doublet and quartet multiplicities were considered for clusters with an odd number of hydrogen or fluorine atoms (odd number of electrons).
The outliers for the singlet residuals are P.vivax for alanine and D.discoideum for phenylalanine, lysine and tryptophan.
Whilst bleaching is often assumed to occur almost exclusively from the longer lived triplet excited state, it is also possible for the singlet excited state to also decay into radical dark states e.g. [30].
Thus the DFT-optimized geometries for the singlet spin states provide the best match for the structure obtained by EXAFS.
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