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A related structure is beta″-alumina, Na2MgAl10O17, where magnesium cations (Mg2+) stabilize the structure and require additional Na+ in the conduction plane for charge compensation.
The Mg2+ co-dopant for charge compensation plays a key role in enhancing the luminescence intensity by a factor of 2.8.
In this work, we present a comprehensive study of the effects of Bi substitution for Pb, along with the formulation of Pb vacancies for charge compensation.
It was inferred that the species responsible for charge compensation for the excess charge capacity must be oxygen ions in these materials, considering that Ni4+ and Ti4+ are generally impossible to be oxidized to a higher valence.
The loss of crystallinity of the tetragonal phase in the Ce-stabilized tetragonal zirconia thin films w.r.t. the tetragonal phase in the unstabilized films was attributed to the oxygen vacancies introduced in the latter due to the need for charge compensation.
The oxidation of the polypyrrole results in the expulsion of solvated protons from the film, via the deprotonation of water; in addition, oxidation of the film is accompanied by a reversible 30% reduction in its thickness, a quite unexpected result in a view of the necessity for charge compensation through ingress of solvated anions.
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The combined feature of easy decomposition and large first de-lithiation capacity demonstrates that Li2NiO2 is a promising positive additive to provide the electric charges/Li+ ions for the charge compensation on negative electrodes.
Experiments in the other alkali metal electrolytes show that the cataion transport, necessary for the charge compensation during redox transitions, cannot be simply related to the size of a cation and the zeolitic structure of indium hexacyanoferrate.
The measured surface areas were 30 × 30 to 80 × 80 μm, and approximately 2 million total ion counts were obtained in acquisition time of about 5 min. A low-energy pulsed electron ion gun (28.0 eV) was used for surface charge compensation.
Of the two, only one cluster accounted for the charge compensation effect between K88E in TaHSP90 and E223K in AtSGT1a (Fig 4A,B).
Furthermore, the K+ current (Kv1.3) that is activated by lipopolysaccharide is inactivated by depolarization, making it unsuitable for mediating charge compensation on a long time scale at positive voltages.
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