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for aqueous samples.
Detection limits for aqueous samples were 0.1 and 0.03 μM for formaldehyde and hexanal, respectively.
A spray chamber operational temperature of 100 °C and a Peltier-cell condenser operational temperature of 2 °C, optimal for aqueous samples, were chosen.
For aqueous samples, 0.5 μL of culture broth supernatant was injected in split injection mode.
The method is based on the U.S. EPA 5030C (purge-and-trap for aqueous samples) method (U.S. EPA 2003) and is accredited by the Australian National Association of Testing Authorities.
Since charge−charge attraction or repulsion is effective only over relatively short distances (the Debye length is approximately 12 Å for aqueous samples at low salt concentrations), the dissociation rate is more likely to be impacted by electrostatics than the encounter rate between the helical state of αS and lipids.
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To minimize solvent loading, the solution uptake rate is reduced to 10 μl/min, far less than the level (85 μl/min) commonly used for aqueous sample introduction with the DIHEN, and oxygen is added to the nebulizer gas flow and outer flow of the ICP.
In-needle extraction was applied for preparation of aqueous samples.
To the best of our knowledge, however, no flow-through PEDD-optrode for assays of aqueous samples in flow analysis or meso/microfluidic devices has been reported so far.
The present study reports a fast and accurate methodology for laser-induced breakdown spectroscopic, LIBS, analysis of aqueous samples for environmental monitoring purposes.
The nanosorbent was employed for cadmium adsorption from aqueous samples.
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