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Now to that list, we can add "Stannous Fluoride Complex", the "unique ingredient" in the mind-blowing new "smart toothpaste" from Oral-B.
In the fluoride complex, both lattice waters are involved in H bonding.
Reaction of [GaCl(L)]⋅2 H2O in aqueous MeCN (unbuffered) with one molar equivalent of aqueous KF leads to complete conversion to the corresponding fluoride complex.
The fluoride complex is stable in the solid state, and for several weeks in aqueous solution (in which the pH was measured to be ca. 4) and in other acidic media.
In fact, the beryllium fluoride complex structure more mimics the ground state of GAP-catalyzed GTP hydrolysis while our structure, obtained by using aluminum fluoride, approximates the subsequent transition-state intermediate.
Notably, during our initial optimisations, the gold fluoride complex 3 was always observed but its formation was suppressed subsequently by controlling the amount and dilution of NEt3 ⋅3 HF.
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The bonds to the highly electronegative fluorine atoms in the fluoride complexes are essentially ionic; and the increase in coordination number, with fluoride ion, from 4 to 6 to 7 for B3+, Fe3+, and Zr4+ is the result mainly of the increase in size of the cation, which permits a successively larger number of fluoride ions to be packed about the central ion.
Conventional treatments produce a final effluent with high quantity of fluoride complexes of iron and chromium.
The proposed method is selective for aluminum fluoride complexes and Al III) in the pH conditions of their occurrence.
Fluoride complexes of metallic ions are one of the main problems when processing industrial effluents with high content of fluoride anion.
It is based on the formation of electroinactive fluoride complexes with Fe(III) and Ce IV) ions decreasing such diffusion current of free metal on boron-doped diamond electrode.
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