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In this approach, the degree of flexibility of the chain is mainly resulting from the relative amount of flexible units constituting the repetition unit of the polymer chain.
The presence of a glycine residue increases the flexibility of the chain and therefore replacing Gly118 with valine would reduce the flexibility of the loop.
Because of the apparent flexibility of the chain attached at C-9, several minima were obtained for 3 by DFT calculations at B3LYP/6 31+G d,p /PCM level.
The elimination of lateral undulations of the vertebral column as the main propulsive agent is accompanied by the development of dorsoventral flexibility of the chain of vertebrae; the distance between successive footfalls is less if the vertebral column remains rigid.
The introduction of a lithium salt in contact with the copolymer chains induces some structure changes which can also be explained by the modification of the degree of flexibility of the chain.
The spectra of a fractionated POIC sample have been analysed in order to find out how the mobility and flexibility of the chain change with increasing temperature, when the polymer turns from the semicrystalline into the liquid crystalline state.
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This can be attributed to the cross-linking of MWCNTs to the fabrics that leads to create a network and this reduces the flexibility of the chains.
We can control the length and the flexibility of the chains.
We quantified the flexibility of the chains by estimating the persistence length (l p) of our rigid (approximately 40 mm or 30 000 σ) and semiflexible (approximately 14 μm or 10 σ, and the Kuhn length was approximately 20 σ; see the Supporting Information) particle chains using Fourier mode analysis.
Polaronic and bipolaronic levels show an ir shift in carboxymethyl cellulose composite attributed to a strong polypyrrole-CMC interaction due to the higher flexibility of the CMC chain than that of PSS chain.
The glass transition and the onset of decomposition temperature of the polymer decrease with the increase of the side chain length and the glass transition is dependent on the flexibility of the side chain introduced.
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