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It is a significant beginning to which the most fitting reaction may simply be: Good enough.
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Re "A Resilient Team Soothes a Nation," July 18: Japan's euphoria in winning the Women's World Cup championship in a thrilling final was a fitting reaction.
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Among the hydrogen storage properties of solid materials, e.g., metal hydrides, the reaction kinetics is of great importance and is often investigated by fitting reaction rate curves to given models.
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Errors on the predicted responses were calculated using a bootstrapping approach in which individual temperature-dependent responses were resampled with replacement and then used to recalculate the best-fitting reaction norm.
This is confirmed by the excellent fitting of reaction data to a kinetic expression describing a second-order reaction proceeding to a position of equilibrium.[ 12] The pseudo first-order rate constants for adduct dissociation (k−1, s−1) could also be calculated as Kexp= k1/ k1/.
The data were fitted to an exponential equation, as described in the 'Materials and methods', and for EcoCas1 a variable floating end point was included to allow fitting as the reaction did not go to completion.
The well-fitting calculations of reaction temperatures for both experiments, reveal a higher independence from reservoir rock composition as compared to classical solute geothermometers.
The code, called GAFit, was also interfaced with the CHARMM and MOPAC programs in order to facilitate force field parameterizations and fittings of specific reaction parameters (SRP) for semiempirical Hamiltonians.
From the fitting results, the apparent reaction rate constants are 0.0013, 0.0057, and 0.0358 min−1 for pristine BiVO4, Bi2O3/BiVO4, and Fe2O3/BiVO4, respectively.
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