Sentence examples for first coordinated to from inspiring English sources

The RAFT agent (1), 4-cyano-4- dodecylsulfanylthiocarbonylsulfanyl pentanoic acid, with an available carboxyl group was first coordinated to the n-TiO2 surface, with the SC(SC12H25) moiety subsequently used for RAFT polymerization of MMA to form the n-TiO2/PMMA nanocomposites.

When the alkoxy group is first coordinated to palladium in the π-olefin complex of 88 and 89, there will be no competing pathway via anti-attack.

In the latter case the base is absent and the palladium apparently prefers to first coordinate to the C=C bond; the resulting species then undergoes a traditional attack from the opposite face as in any classical electrophilic addition.

Based on our results, oxygen first coordinates to the ferric center at a vacant site generated by partial dissociation of the catecholate substrate, which is simultaneously oxidized to a semiquinone by oxygen, with the iron center acting as an electron buffer.

In this tandem reaction the iridium catalyst is required for both conversions: it acts as the Lewis acid in the Nazarov cyclization and in the next step the nitro group of nitrostyrene first coordinates to iridium in a ligand exchange with the carbonyl ester oxygen atom before the actual Michael addition takes place to the opposite face of the R-group.

Electrophilic Pt II) complexes efficiently initiate the cation olefin reaction by first coordinating to the alkene with selection rules that favor less substituted alkenes over more substituted alkenes.

A structural model has been proposed for the function of human homotrimeric hCtr1 in which Cu(I) first coordinates to the methionine-rich motif in the hCtr1 extracellular amino (N -terminus aN -terminusonserved methionine residue upstreandof thenfirst transmembrane domain is essential for conservedort [ 33, 34].

In the case of the hexa-monodentate thiazolyl ligand 4, only every second ring is coordinated to a silver cation.

Thus, one oxygen atom (O2) of the remaining OMc ligands bridges Cd1 and Cd1′, and the second (O3) is coordinated to Cd2.

In addition to the signals for the free btz ligand, signals were also observed for a second btz ligand, still coordinated to the metal.

where the indices 55 64 for the first coordinate correspond to the numerical characters 0 9 and the indices 55 64 for the second coordinate indicate the last ten locations on the keyboard.