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Honeycomb-structured thin films have been usually fabricated by the breath figures method with a polymer like PS [18].
To maintain the spherical orientation of the droplets over the solution, the breath figures method requires immiscibility between the solvent and the water [25].
During the breath figures method, due to the high humidity within the closed chamber, water droplets were condensed on the surface of the polymer solution.
These arrays can be easily generated by removing the top portion of the honeycomb films prepared by the breath figures method.
Economical and self-assembling polystyrene 'Breath Figures' method has been used to obtain a large polymeric 3D honey-comb structure substrate successively coated with metallic ductile films with thickness of few hundreds of nanometers deposited via DC magnetron sputtering.
For the breath figures method, a highly organized, hexagonal thin film, called a honeycomb film, is induced by the evaporation of organic solvent after water droplets sink into the polymer solution.
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Furthermore, the traditionally breath figure method was modified by decreasing the substrate temperature below 0 °C.
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