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Additionally, although the five fiber set comprises five of the six different fiber coatings evaluated, it is also noteworthy that the inclusion of the sixth fiber coating (85 µm PA) is not as effective as inclusion of the 75 µm CAR-PDMS fiber (Table 4).
The loose entanglement from the thin silane coatings cannot induce an increased strength between the fiber coating and matrix so that the fibers are easier to be pulled out.
An absorbed amount of analytes on fiber coating and sensitivity depend on sorption kinetics and partition coefficient between fiber coating and a sample (Yang and Peppard 1994).
PDMS is the most common fiber coating for the analysis of HOCs.
Different parameters affecting extraction efficiency such as extraction mode, fiber coating and temperature were studied.
Based on the findings, the interfacial properties with PyC fiber coating can be predicted.
The results showed that temperature and fiber coating were the most significant variables affecting extraction efficiency.
The other parameters such as type of fiber coating, pH and derivatization conditions were also evaluated.
Both factors, fiber coating and extraction temperature, were important to achieve high sensitivity.
Polyacrylonitrile (PAN /C18 bonded fuse silica was used as the fiber coating for LC applications because the fiber coating was not swollen in common LC solvents at room temperature.
A carboxen/polydimethylsiloxane (CAR-PDMS) fiber coating was found to be the most suitable for the analysis of emulsion volatiles.
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