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Cekovic, Z., Dimitrijevic, L., Djokic, G. & Srnic, T. Remote functionalization by ferrous ion cupric ion induced decomposition of alkyl hydroperoxides.
The initial reduction product is adsorbed ferrous ion, Feads2+.
Results suggest that the addition of ferrous ion would activate the persulfate oxidation.
Preliminary in vitro antioxidant activity was studied by Ferrous ion Oxidation-Xylenol orange (FOX) method.
Previous studies reported HIF stabilizers include CoCl2 and DFX, two representative ferrous ion antagonist, or DMOG, a competitive inhibitor of Prolyl hydroxylase.
Cekovic, Z. & Cvetkovic, M. Functionalization of the delta-carbon atom by the ferrous ion induced decomposition of alkyl hydroperoxides in the presence of cupric salts.
One of them was the simultaneous reduction of ferric oxide to ferrous ion and metallic iron.
This effect was greater in a ligand that forms more stable complex with ferrous ion.
Ferrous ion initial concentration is the second variable in importance.
FRAP values were calculated as microgram per milliliter ferrous ion (ferric-reducing power) and are presented as milligram per kilogram of Fe2+E (ferrous ion equivalent).
Once the ferrous ion was exhausted, the solution was stood, filtered.
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