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Not included in the optimization were, e.g., the numbers of protein copies which were set to fixed values, the vesicle size, and the details of the fastest reactions inside the bc1 complexes (see table S1).
Electron transfer from α-amino radicals to vicinal dicarbonyl compounds is regarded as one of the fastest reactions between a radical and a neutral closed-shell organic molecule.[ 28] Alloxan (3 a) reacts as an amide tautomer, thus allowing stabilization of a developing oxyanion character, a feature which is impossible for the inactive 3 b (Table 1, entry 3).
In addition, we found that Σ Ereact,opt is larger than ETS for some of the fastest reactions involving TCO*, which would imply the absence of any activation barrier and is an artefact from overlooking the formation of a favourable van der Waals complex prior to the reaction.
Those with the fastest reactions will always win because he who shoots first almost always wins.
Similar(55)
The fastest reaction times of all, claims Mr Partnoy, are needed in fencing.
Among these reactions the water gas shift reaction is the fastest reaction step.
This method uses explicit time stepping, so the step size is controlled by the fastest reaction.
In the case of each enzyme, the assays containing 8V Chlide demonstrated the fastest reaction rates.
Thus, the iodides as the best leaving groups lead to the fastest reaction.
The fastest reaction evoked by SWCNTs in macrophages was an oxidative stress that occurred within hours (Kagan et al. 2006).
He needs fast reactions, and energy for the hours ahead.
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