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In solution, a fast equilibrium between both keto-enol forms exists.
The central feature of the mechanism is the fast equilibrium between monomers and the magic-sized clusters.
These features additionally confirmed our results concerning the fast equilibrium between both stereoisomeric peptides.
ATRP is based on the use of a transition metal complex, which mediates a fast equilibrium between dormant and active species (Scheme 1).
Alternatively, a Brownian Ratchet (full, red lines) is composed of two orthogonal transitions: a fast equilibrium between pre- and post-translocated states along the mechanical coordinated, followed by a 'rectifying' chemical transition.
For acetaminophen, which is a moderately lipophilic compound with known fast equilibrium between blood and brain, and no indication of active transport at the BBB or BCSFB, we expected the brain ECF and CSF concentrations to be similar.
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The use of tracer 25(OH D prevents the continued production of labelled 25(OH D from labelled vitamin D and allows the establishment of faster equilibrium between body pools.
Under this condition, a fast equilibrium is built between open and closed states with the equilibrium constant Kop, which describes the extent of proton accessibility by the solvent and the inverse of which (namely the protection factor, P = 1/Kop = kint/kex) reveals how well the proton is protected from the solvent.
The spectra in Figure 4 could indicate that a fast equilibrium is established between radical species that are subject to further reaction.
A fast equilibrium state approach to determine the interaction between stochastic crosswinds and a high-speed train is presented in this paper.
However, the fast equilibrium state approach is approximately 3 times faster than the alternative co-simulation.
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