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Pyrogram a) corresponds to the external sample, pyrogram b) corresponds to the bulk area.
Additionally, we demonstrated that the SRS of MC Cu pillars increases with decreasing size up to a certain limit and then decreases with a further decrease in the external sample size; thus, a maximum SRS emerges.
A phenomenological model was proposed to rationalize the scaling behavior of the activation volume with the external sample size and to highlight the effect of the internal feature size on the rate-limiting behavior of conventional bulk nanostructured metals (Cu).
In fact, it has been shown that in single crystals the ultimate tensile strength and the yield strength scale with external sample size in a power law fashion, sometimes attaining a significant fraction of material's theoretical strength, and exhibiting the now-commonly-known phenomenon "smaller is stronger".
Again, we optimized the parameters C and ϵ (we used a 10-fold cross-validation repeated 2 times to select the best parameter combination in the inner loop) and trained a model for each of the n leave-one-out sets and predicted the external sample for each model.
The new model is then applied to this external sample to obtain an independent estimate of the predictor's accuracy.
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Because the SC was kept floating, the external sampling equipment requires no electric connection.
In the thoracolumbar and lumbar vertebrae, external samples were also cored.
Holdout with training proportions from 80 to 20% are used and external samples are generated for more challenging tests.
Future works should be focused both to increase the variability of the diet ingredients and also to validate the models with external samples.
The models developed by NIR in association with multivariate analysis provided good prediction of the APIs for the external samples and were therefore validated.
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