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In the presence of oxygen, the linewidth of the EPR lines is broadened; the extent of broadening depends on pO2 (Swartz et al, 1993; Swartz and Clarkson, 1998).
In the presence of oxygen, the line-width of the EPR lines is broadened; the extent of broadening depends on pO2 (Swartz et al, 1993; Swartz and Clarkson, 1998).
The extent of broadening of bicarbonate was significantly reduced at higher MES buffer concentrations (not shown), suggesting that the HCO3− broadening is likely to come from general base catalysis of CO oxidation.
The extent of broadening was similar to that of the CO resonance, but given the high concentrations of bicarbonate which accumulated at high pD (measured directly in the NMR experiment to be >50 mM), the resulting exchange rates are ∼100 times higher than those for CO.
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There's been a lot of broadening.
This process signified the possibility of broadening clinical service offerings.
Since the extent of the broadening increases almost linearly with the number of creep deformation, the measurement of the broadening by X-ray diffraction can be utilized in non-destructive methods to predict the lifetime of Ni-base superalloys.
The extent of line broadening was insufficient for species with 1/ kF values greater than 0.7 μs and in cases where a "P18A undocked from Trp6" state does not become populated (χU ≥ 0.08) at temperatures below 310 K.
The extent of line broadening is also 10−20% of that observed with the native protein, indicating (as expected) that only the active protein catalyzes the isotopic exchange, and forms that contain partially assembled active sites (80−90%) do not give rise to broadening of CO due to binding or collisions with CODH-II.
In some cases, dynamics were measured at pH 2.5 to take advantage of the fold destabilizing effect of Asp1,9 protonation (ΔΔ G = 3.1 kJ/mol) to increase the unfolded state population and thus increases the extent of exchange broadening that can be observed providing folding rate constants with greater precision.
The extent of narrowing or broadening of the emission line width provides information on the quality of size distribution of the materials as well as surface defect states.
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