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Figure 5 TEM photo of bioPd(0) at different standing time in the extending reduction process.
This observation further confirmed the results in Figure 4. Figure 4 Effect of the standing time in the extending reduction process on the catalytic activity of bioPd(0).
TEM photo of bioPd(0) collected at a standing time of 6 h (a,c) and collected immediately (b,d) in the extending reduction process.
The effect of the shaking speed and the shaking time in the extending reduction process to the conversion of the reduction of Cr VI) to Cr III) with the bioPd(0) as catalyst (b).
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The effect of fluid shear stress on bioPd(0) catalytic activity varied among the adsorption, reduction, and extended reduction process.
And then the influence of the shaking time on the catalytic activity in the extended reduction process was investigated.
The fluid shear stress in the extended reduction process could affect the catalytic activity of bioPd(0) significantly.
It is concluded that a high bioPd(0) catalytic activity can be achieved by controlling the fluid shear stress intensity in an extended reduction process in the bioreactor.
Stationary operation in the extended reduction process referred to the cell/Pd(0)/Pd II) mixture solution being allowed to stand from 0 to 13 h.
The influence of standing time on the extended reduction of Cr VI) to Cr III) by bioPd(0) catalytic activity was given in Figure 4.
The Cr VI) reaction ratio changed with different types of bioPd(0) catalyst and was solely attributed to the different shaking speeds in the extended reduction process.
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