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For example in Scheme 1, Rxns 1 and 2 are the primary competing pathways for the thermal degradation of nicotine.
The decarboxylation of pyruvate to acetaldehyde (Scheme 1) conducted by yeast pyruvate decarboxylase (YPDC, EC 4.1.1.1) is shown as an example in Scheme 1.
As evidenced by the example in Scheme 1, while the method is convenient for the synthesis of benzohydroquinones such as 3, it proves cumbersome when targeting the regioisomeric series 7.
For example in scheme (b), P Q j = 1 | L i) and P L i) were computed using the subjects recruited online (n = 100) and used to classify subjects recruited at the clinic (n = 62).
As noted above, the oxidation reaction is highly stereoselective and for each example in Scheme 1 and Scheme 10, the thermodynamically favoured isomer is the dominant product (see the Supporting Information for DFT calculations on each structure).
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In the hypothetical examples in Scheme 4, the donor substrate is pyruvate and, thus, only one new stereogenic centre is formed.
The example provided in Scheme 6 makes use of methyltrityl protection, which can be selectively removed by washing with 1% TFA in dichloromethane.
For example, in the scheme proposed by Kim [31], using the inscribed circle of images as a unit circle, when subjected to a shear attack, an accurate unit circle cannot be found, leading to the failure of watermark extraction.
For example, in the scheme proposed in [21], based on an union of MDCTs, the observed vector x represents several seconds of the music signal sampled at 44.1 kHz and typical values could be N > 105, L > 106, and K ≈ 103.
For pragmatic reasons, all of the examples presented in Scheme 2 were performed using 5 mol % of the catalyst.
The different examples presented in Scheme 13 illustrate the potential of the method for the synthesis of azaGly peptides or lipopeptides with an azaGly linker between the lipid moiety and the peptide.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com