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Casting trials performed with this substance revealed an evident phase separation and Tg of starch did not appear really modified by its presence.
For the PI/nph-LPSQ films, no evident phase separation was observed according to the SEM results, even when the nph-LPSQ content reached 30 wt%, which resulted in mechanical properties improved by increasing the nph-LPSQ content.
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This is evident from a phase separation of dilute GLFG solutions (e.g., 2 mg/ml) into a protein-rich and an aqueous phase (S Frey, unpublished results, 2007).
Diffraction patterns for both blend systems show clear evidence of phase separation at ϕ=0.20 and higher, but no significant phase separation is evident at ϕ=0.10 and lower.
Widespread phase separation was evident and a range of morphologies recorded.
Comparing the melting values before and after treatments, it becomes evident that there is no phase separation using the atmospheric plasma treatment or white spirit washing, when used to modify the zinc stearate in the TPU powder.
This phase separation is more evident in the case of high glycerol levels in the TPS (>24% glycerol).
Within the polybutadiene-rich central layer, lateral phase separation is also evident, with polystyrene-rich domains of oblate spheroidal shape.
In precipitates formed during slow cooling from higher-temperature anneals, nano-scale phase separation and intermetallic phases are evident, suggestive of a high-temperature transition through a liquid phase.
It was observed that a post-annealing treatment favors the phase separation in hafnium silicate matrix being more evident at 950°C.
Direct acidification during gelation produces a variation in bulk modulus and work to fracture of the gels, with phase separation of the gel and the solvent being evident for all the high acyl to low acyl proportions at pHs less than 3.
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