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The NH spacer groups in the PNP ligands are responsible for the establishment of hydrogen bonds that determines the solid state supramolecular architectures.
We demonstrate that MPSA enables the consideration of energetic and economic aspects simultaneously in the system design and hence supports the establishment of hydrogen energy conversion systems.
We report that PCPP can spontaneously self-assemble into intermolecular complexes with common formulation excipients − polyethers in aqueous solutions at neutral pH through the establishment of hydrogen bonds.
From FTIR data, the polymer compatibility could be attributed to the establishment of hydrogen bonds, and dipole ion interactions between carboxylic groups, sulfonate groups, and sodium ion on the polymer segments.
In this paper, we utilize Analytic Hierarchy Process to rank, on the basis of several supply, demand and environmental criteria, the more than 750 municipalities of Andalusia according to their suitability for the establishment of hydrogen fueling stations.
This behaviour is obviously due to the excellent compatibility between BC and PHEMA that arises from the potential establishment of hydrogen bonds between them.
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It is obvious from the crystal structure that the proton should be on N6 to allow the establishment of a hydrogen bond with the protein.
This helix repacking leads to the lowering of the p Ka of Asp96, which is initially high (>12), and the establishment of a hydrogen-bonded chain to the Schiff base, which together facilitate the reprotonation of the Schiff base from the cytosol.
This is due to the great structural alteration required for the establishment of strong intramolecular hydrogen bonds between axial groups.
This is probably associated with the establishment of strong interactions (hydrogen bonds) between BC nanofibrils and PHEMA chains.
Our structural and thermodynamic analyses have led us to the conclusion, having once ruled out any possible ionization events or conformational changes coupled to the association, that the establishment of a complex hydrogen-bond network mediated by water molecules buried at the binding interface is responsible for the observed thermodynamic behaviour.
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