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Figure 1 ESR spin-trapping with 100 mM DMPO.
The problem with using ESR spin-trapping with DMPO is its susceptibility to artifacts.
To evaluate whether pyrite generates OH when it is suspended in water, experiments were performed using ESR spin-trapping in the presence of dissolved molecular oxygen.
Pyrite has been previously shown to form hydroxyl radicals when it is in aqueous suspension using ESR spin-trapping with DMPO [30].
Using a combination of electron spin resonance (ESR) spin-trapping techniques and scavenging reactions involving nucleic acids, the formation of hydroxyl radicals in pyrite/aqueous suspensions is demonstrated.
The photochemical properties as well as the chemical mechanisms associated with these catalysts are investigated by ESR spin-trapping, laser flash photolysis, steady state photolysis, cyclic voltammetry and luminescence experiments.
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NO release from NOBL-1 induced by blue light was confirmed by means of ESR spin trapping method with iron-dithiocarbamate complex.
The results of the ESR spin trapping experiments show conclusively that OH is formed spontaneously in pyrite slurries in the presence of molecular oxygen.
The transient species including singlet oxygen, superoxide radical anion, M-PPV triplet state, M-PPV radical cation and anion in M-PPV photodegradation were observed and characterized systematically with ESR spin trapping, pulse radiolysis, and laser flash photolysis techniques.
Using the technique of electron spin resonance (ESR) spin trapping, we have confirmed that the primary damaging species produced on irradiation of TiO2 nanoparticles is the hydroxyl (OH) radical.
The reactions of various chromate pigments and ascorbate were investigated by an ESR spin trapping technique.
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