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The analytical solution for the limiting behaviour under equilibrium control conditions as well as a closed-form analytical approximation for long time asymptotic behaviour are derived.
In order to exclude the intrusion of nonlinear equilibrium control effect it is necessary to consider simultaneously experimental response curves at different flow rates.
The advantages and weaknesses of representative reaction systems are analyzed, while the challenges and opportunities to engineering application of the equilibrium control based on reversible covalent chemistry for producing end-use polymers are summarized.
As it allows a large variety of options in terms of real-time analysis and control schemes, its commissioning has been carried out in three phases: equilibrium control, toroidal field control, and MHD mode control.
Micropore diffusion control as a rate determining event is a more satisfactory model for representing the pressurizing and depressurizing of the column with N2 or O2 in the presence of the 5A zeolite packing than a model based on equilibrium control.
The schemes include: plasma equilibrium control and resistive wall mode stabilization, aiming at controlling actively the discharge when the passive action of the shell vanishes; the rotation of the localised helical deformation to minimize the enhanced plasma wall interaction; the MHD mode control and the 'intelligent shell', aiming at achieving a better comprehension of the underlying physics.
Similar(48)
The equilibrium controlled water dissociation and the kinetically controlled nitrous oxide (N2O) decomposition were studied in the perovskite BaCoxFeyZr1−x−yO3−δ (BCFZ) oxygen-permeable membrane reactor.
It is shown that equilibrium controlled systems yield response curves which are qualitatively similar to those obtained under conditions of kinetic control.
The pH of the leachate during the initial flushing with water lay between 3.8 and 4.4 suggesting that the jarosite/schwertmannite equilibrium controls the solution chemistry.
Equilibrium controlled sorption (organic carbon partition coefficient of 52 ml/g) and a half-life of between 7.5 and 15 weeks were considered for atrazine.
Textural equilibrium controls the distribution of the liquid phase in many naturally occurring porous materials such as partially molten rocks and alloys, salt brine and ice water systems.
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