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All the rare-earth metals form the sesquioxide at room temperature, but it may not be the stable equilibrium composition.
The optimal P/D ratio for the equilibrium composition core is in between 1.53 and 1.59.
For the second step, however, the change in Gibbs energy is negative; its magnitude depends on the equilibrium composition of the mixture.
Equilibrium composition profiles are predicted in both confined and large systems using the Landau Ginzburg functional.
The corresponding vapour-liquid equilibrium composition is also shown so that pervaporation and flash distillation could be compared.
The equilibrium composition of γ-Nb4N3±x in this temperature interval is depending on the temperature only 42 44.0 at.% N, hence the transition occurs also in samples with a non-equilibrium composition.
Thermodynamic calculations were performed to assess the reversibility of the reactions and the equilibrium composition of the reaction mixture.
Selectivities close to equilibrium composition were obtained in most cases except at the very low space times.
An algorithm which gives very good first trial values for the computation of chemical equilibrium composition is proposed.
The thermochemistry proposed here is shown to predict substantially different equilibrium composition from the thermochemistry previously available in the literature.
The coarsening stage leads to a steady-state size distribution of niobium carbonitrides of the equilibrium composition.
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