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It is argued that the EWF response is governed by the entanglement network density.
Increasing Mw above 18.9 × 104 resulted in enhanced entanglement network strength and strain-hardening.
Both mechanisms are evaluated quantitatively by calculating the entanglement network and pore size of buckypaper.
The (more classical) second stage is a progressive embrittlement due to the destruction of the entanglement network.
Embrittlement in these layers is presumably linked to the degradation of the entanglement network in the amorphous phase.
Finally, by mapping the parent polymer chains to primitive paths through direct geometrical algorithms, we analyse the characteristics of the entanglement network as a function of packing density.
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Solutions of PB form entanglement networks which retard the reorientation of the PHIC molecules.
The decrease of the relaxation strength can be attributed to the reduction of the effective dipole moment due to the restriction of motions of the PHIC chains in entanglement networks of PB chains.
The results showed that during soaking in NaCl aqueous solution the PVA chain-entanglement network was formed and the water was included into the PVA chain-entanglement network.
The relationships between G′ or G″ and frequency were observed to plateau at higher frequencies, which is indicative of polymer chain entanglement and network formation.
The swelling kinetics decreased with increasing PEI and PAA concentrations because of the high molecular entanglement and network density associated with ionic interaction between PAA and PEI molecules.
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