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This zone was followed by a sulphur enriched zone (2 5 mm deep), which then again partially overlapped with a following chlorine enriched zone (approximately 50 mm deep).
The hydrogen enriched zone can be ascribed to a region of increased local defect density.
All concretes showed a 200 300 μm deep magnesium enriched zone containing negligible amounts of sulphur and chlorine at the surface.
Here the CO2 and alkali element enriched zone is much thinner (< 100 m), is less enriched in these elements (e.g. by a factor of three for CO2), and has lower 87Sr/86Sr and δ7Li.
During the growth cycle a portion of the macroalgae and the associated biota from the culture lines will be lost to the benthos either through erosion of the blade tips or shearing of cultured material creating an organically enriched zone [ 56].
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These sedimentary facies and weathering crust zones are mostly enriched zones for natural gas (Cai et al. 2008; Jin 2010, 2012).
Back scattered electron images of the P enriched zones indicated that the P solids occurred as distinct authigenic grains (up to 300 μm diameter) and as grain coatings.
Bone transcripts were enriched in zone II and zone III, respectively, when compared to zone I. Core genes found in these groups included Bmp7, parathyroid hormone receptor 1 (PTnfsf11Tnfsf11, and Ibsp, which are prototypical markers of EO (Table S1 7, S3 12, see supplemental data) [60].
The remaining 15 gene sets exhibited different enrichment patterns that, with the exception of the proteasome pathway (which was similarly enriched in zone III and day 9), showed similar enrichment in zone II and day 15 of MM culture (Table S5 3,4, see supplemental data).
Cartilage genes, molecular chaperones, metabolic genes and genes involved in gluconeogenesis were enriched in zone II (Table S2 2 5,-9 S2 2 5,-9lemental data).
The cartilage genes enriched in zone III vs. I contained a different subset of transcripts including Dmp1 and Mmp13, which we had identified in a previous study [29] and/or confirmed with qRT-PCR analysis.
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