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A significant improvement in the electrocatalytic property of nano-Ag derived composite coatings was found, and was attributed to the enhanced electroactive sites of Ag particles.
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This architecture designed is expected to enrich accessible electroactive sites, faster kinetics of NiO/NiOOH redox pair, as well as enhance participation degree of NiO during the charging/discharging process.
(2) For redox reactions, the nanotube arrays could result in more exposed electroactive sites.
Finally, the XMoO4 nanosheets and the NiCo2O4 nanosheets are mesoporous that increases the electroactive sites.
The dopamine@CNT hybrid (denoted as DA@CNT) reveals an enhanced electrocatalytic activity towards ORR with highly positive onset potential and cathodic current as a result of their outstanding features of longitudinal mesoporous structure, high surface area, and ornamentation of DA layers with nitrogen moieties, which enable fast electron transport and fully exposed electroactive sites.
The obtained NiCo2O4/RGO nanocomposite with loose layered structure exhibits a large surface area, increased electronic conductivity and more electroactive sites.
The core/shell heterostructure endowed the NiCo2S4@PANI/CF composite materials with high electron diffusion efficiency and abundant accessible electroactive sites.
The solid-state voltammetry of the material had suggested that the two electroactive sites were present.
Moreover, nitrogen doping can generate different types of defects and vacancies, thereby providing more electroactive sites.
A large specific surface area in redox energy storage supercapacitors ensures an efficient contact with more electroactive sites even at high current densities [26, 27].
It helps the electron exchange reaction between electroactive sites, but hinders the diffusion of counter ions.
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