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Nanomaterials have become attractive as adsorbents because they have a high surface area, enhanced active sites, and excellent sorption capacity.
Herein, a novel strategy for synthesis of highly porous nitrogen-sulfur co-doped graphene nanoribbons (NS-GNRs) with enhanced active sites was developed.
These CuO nanostructures had a large surface area, approximately 60 m2 g-1, and the effects of their enhanced active sites by nanostructuring on the electrochemical performance of CuO could be further realized by the incorporation of MWCNTs.
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The impressive catalytic performance of the catalyst is attributed to the unique mesoporous metal-core/graphene-shell architecture in which high interactions between two transition metals and transition metal-carbon synergistically provide enhanced catalytically active sites, accelerate interfacial charge transfer, and optimize oxygen adsorption energy.
The hysteresis can be better explained by the enhanced stability of active sites under reaction conditions.
Earlier studies have shown that the hybrid structures offer enhanced catalytic activity with more active sites [13].
Analysis from the energetic and structural assays indicated that the enhanced interactions between the active sites and the substrate in the transition state led to improved catalytic efficiency.
Based on the UV-Vis spectrum, nitrogen sorption and IPCE analysis, the improved performance can be attributed to the enhanced scattering and increased active sites for dye loading.
By doping abundant nitrogen (about 5 wt%), the mesoporous carbon shells provide more active sites, enhanced electrical conductivity and electrode infiltration, and avoid the Co nanoparticles agglomeration and serious electrode dissolution.
The relationship of the current at 0.3 V versus the microscopic surface area showed a positive deviation from the linearity indicating the enhanced exposure of surface active sites for the glucose oxidation.
The improved photocatalytic performance benefits from the tubular structure and the nitrogen defects, which lead to the improved optical absorption, more exposed active edges, nitrogen defects active sites, enhanced charge transfer and separation efficiency, higher surface area, fast and long-distance electron transport, and longer fluorescence lifetime.
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CEO of Professional Science Editing for Scientists @ prosciediting.com